Determination of cation distribution in (Co,Ni,Zn)2SiO4 olivine by synchrotron X-ray diffraction     

K. Tsukimura  S. Sasaki 《Physics and Chemistry of Minerals》2000,27(4):234-241

 The cation distribution of Co, Ni, and Zn between the M1 and M2 sites of a synthetic olivine was determined with a single-crystal diffraction method. The crystal data are (Co_0.377Ni_0.396Zn_0.227)₂SiO₄, M _r  = 212.692, orthorhombic, Pbnm, a = 475.64(3), b = 1022.83(8), and c = 596.96(6) pm, V = 0.2904(1) nm³, Z = 4, D _x  = 4.864 g cm⁻³, and F(0 0 0) = 408.62. Lattice, positional, and thermal parameters were determined with MoKα radiation; R = 0.025 for 1487 symmetry-independent reflections with F > 4σ(F). The site occupancies of Co, Ni, and Zn were determined with synchrotron radiation employing the anomalous dispersion effect of Co and Ni. The synchrotron radiation data include two sets of intensity data collected at 161.57 and 149.81 pm, which are about 1 pm longer than Co and Ni absorption edges, respectively. The R value was 0.022 for Co K edge data with 174 independent reflections, and 0.034 for Ni K edge data with 169 reflections. The occupancies are 0.334Co + 0.539Ni + 0.127Zn in the M1 sites, and 0.420Co + 0.253Ni + 0.327Zn in the M2 sites. The compilation of the cation distributions in olivines shows that the distributions depend on ionic radii and electronegativities of constituent cations, and that the partition coefficient can be estimated from the equation: ln [(A/B)_M1/(A/B)_M2] = −0.272 (IR _A -IR _B ) + 3.65 (EN _A −EN _B ), where IR (pm) and EN are ionic radius and electronegativity, respectively. Received: 8 April 1999 / Revised, accepted: 7 September 1999  相似文献   

Regionality and seasonality of submesoscale and mesoscale turbulence in the North Pacific Ocean   总被引：1，自引：0，他引：1  

Hideharu Sasaki  Patrice Klein  Yoshikazu Sasai  Bo Qiu 《Ocean Dynamics》2017,67(9):1195-1216

The kinetic energy (KE) seasonality has been revealed by satellite altimeters in many oceanic regions. Question about the mechanisms that trigger this seasonality is still challenging. We address this question through the comparison of two numerical simulations. The first one, with a 1/10° horizontal grid spacing, 54 vertical levels, represents dynamics of physical scales larger than 50 km. The second one, with a 1/30° grid spacing, 100 vertical levels, takes into account the dynamics of physical scales down to 16 km. Comparison clearly emphasizes in the whole North Pacific Ocean, not only a significant KE increase by a factor up to three, but also the emergence of seasonal variability when the scale range 16–50 km (called submesoscales in this study) is taken into account. But the mechanisms explaining these KE changes display strong regional contrasts. In high KE regions, such the Kuroshio Extension and the western and eastern subtropics, frontal mixed-layer instabilities appear to be the main mechanism for the emergence of submesoscales in winter. Subsequent inverse kinetic energy cascade leads to the KE seasonality of larger scales. In other regions, in particular in subarctic regions, results suggest that the KE seasonality is principally produced by larger-scale instabilities with typical scales of 100 km and not so much by smaller-scale mixed-layer instabilities. Using arguments from geostrophic turbulence, the submesoscale impact in these regions is assumed to strengthen mesoscale eddies that become more coherent and not quickly dissipated, leading to a KE increase.  相似文献   

Solute transfer during consolidation based on a solid‐fluid‐solute coupling model          下载免费PDF全文

Shun Nomura  Katsuyuki Kawai  Shinya Tachibana  Atsushi Iizuka 《国际地质力学数值与分析法杂志》2018,42(10):1172-1196

The migration of contaminant through soil is usually modeled using the advection‐dispersion equation and assumes that the porous media is stationary without introducing a constitutive equation to represent soil structure. Consequently, time‐dependent deformation induced by soil consolidation or physical remediation is not considered, despite the need to consider these variables during planning for the remediation of contaminated ground, the prediction of contaminated groundwater movement, and the design of engineered landfills. This study focuses on the numerical modeling of solute transfer during consolidation as a first step to resolve some of these issues. We combine a coupling theory‐based mass conservation law for soil‐fluid‐solute phases with finite element modeling to simulate solute transfer during deformation and groundwater convection. We also assessed the sensitivity of solute transfer to the initial boundary conditions. The modeling shows the migration of solute toward the ground surface as a result of ground settlement and the dissipation of excess pore water pressure. The form of solute transport is dependent on the ground conditions, including factors such as the loading schedule, contamination depth, and water content. The results indicate that an understanding of the interaction between coupling phases is essential in predicting solute transfer in ground deformation and could provide an appropriate approach to ground management for soil remediation.  相似文献   

Vertical coupling and dynamical source for the intraseasonal variability in the deep Kuroshio Extension     

Yang  Yang  Liang  X. San  Sasaki  Hideharu 《Ocean Dynamics》2021,71(11-12):1069-1086

Ocean Dynamics - In the power spectrum, the upper and deep parts of the Kuroshio Extension have distinctly different peaks. The former peaks around 200 days, while the latter is mainly at the...  相似文献   

Surface morphological features of boulders on Asteroid 25143 Itokawa     

Takaaki Noguchi  Akira Tsuchiyama  Hirohide Demura  Hideaki Miyamoto  Tomoki Nakamura  Sho Sasaki  Takashi Kubota  Michael E. Zolensky 《Icarus》2010,206(1):319-326

On the sub-kilometer S-type asteroid, 25143 Itokawa, some boulders on rough terrains seem to be exposed without any powdery material covering. Based on surface morphological features, there are two major types of boulders: one has rounded edges and corners (rounded boulders), while the other has angular edges and corners (angular boulders). The surface features of the rounded boulders suggest that they have hardness heterogeneity and that some may be breccias. The angular boulders appear to be more resistant to impact disruption than the rounded ones, which may be due to a difference in lithology. The major constituents of Itokawa may be LL chondrite-like brecciated lithology (rounded boulders) along with a remarkable number of boulders suggesting that lithology is atypical among LL chondrites (angular boulders). Some of both types of boulders contain intersecting and stepped planar foliations. Comparison with meteorite ALH76009 suggests that the planar foliations may be marks where rocks were torn apart. As lithified breccias cannot be formed on present-day sub-kilometer-sized Itokawa, it is reasonable that boulders with various lithologies on Itokawa were formed on its large ancestor(s). The rubble-pile structure of Itokawa suggested by its low density (∼1.9 g/cm³) indicates that boulders on Itokawa are reassembled fragments formed by catastrophic disruption of large ancestor(s).  相似文献   

Impact of the equatorial Atlantic sea surface temperature on the tropical Pacific in a CGCM   总被引：1，自引：0，他引：1  

Wataru Sasaki  Takeshi Doi  Kelvin J. Richards  Yukio Masumoto 《Climate Dynamics》2014,43(9-10):2539-2552

Many coupled general circulation models (CGCMs) suffer from serious model bias in the zonal gradient of sea surface temperature (SST) in the equatorial Atlantic. The bias of the equatorial Atlantic SST (EASST) may affect the interannual variability of the equatorial Atlantic, which in turn may influence the state of the tropical Pacific. In this paper we investigate the impact of the bias and the interannual variability of the EASST on the tropical Pacific in a CGCM. To determine the impact of the interannual variability of the EASST on the tropical Pacific, we compare a run in a fully coupled mode (CTL run) and a run in which the EASST is nudged toward the climatological monthly mean of the SST in the CTL run, but full air-sea coupling is allowed elsewhere (AT_m run). We find that, when the interannual variability of the EASST is excluded, the thermocline depth in the eastern equatorial Pacific is deepened, and the amplitude of the El Niño/Southern Oscillation is reduced by 30 % compared to the CTL run. The impact of the bias of the EASST on the tropical Pacific is investigated by comparing the AT_m run and a run in which the EASST is nudged toward the observed climatological monthly mean SST (AT_o run). It is found that, when the bias of the EASST is removed (i.e. AT_o run), the Gill–Matsuno type response to the warm SST anomalies in the western equatorial Atlantic induces low-level cyclonic anomalies in the eastern South Pacific, which leads to a deeper thermocline and colder SST in the South Pacific as compared to AT_m. The colder SST in the South Pacific reduces the precipitation along the South Pacific convergence zone. Our results of the model experiments demonstrate the importance of the EASST to the tropical Pacific climate.  相似文献   

Visible and near-infrared spectral survey of Martian meteorites stored at the National Institute of Polar Research     

Takahiro Hiroi  Hiroshi Kaiden  Keiji Misawa  Takafumi Niihara  Hideyasu Kojima  Sho Sasaki 《Polar Science》2011,5(3):337-344

Martian meteorite chip samples stored at the National Institute of Polar Research (NIPR) have been studied by a visible and near-infrared (VNIR) spectrometer. Measured spots are about 3 × 2 mm in size, which are clearly marked on photographs of the meteorite chips. Rock types and approximate mineral compositions of studied meteorites have been identified or obtained through this spectral survey with no sample preparation required. This study demonstrates that this kind of spectral survey is effective in classifying and describing Marian meteorites, and that such a VNIR spectrometer on a Mars rover would be useful for identifying these kinds of unaltered Mars rocks. Further studies which utilize a smaller spot size are desired for improving the accuracy of identifying the clasts and mineral phases in the rocks.  相似文献   

A multidimensional horizontal-loop controlled-source electromagnetic inversion method and its use to characterize heterogeneity in aquiferous fractured crystalline rocks   总被引：1，自引：0，他引：1  

Yutaka Sasaki  Max A. Meju 《Geophysical Journal International》2006,166(1):59-66

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Stable isotope and petrologic evidence for open-system degassing during the climactic and pre-climactic eruptions of Mt. Mazama, Crater Lake, Oregon     

Charles W. Mandeville  James D. Webster  Bruce E. Taylor  Akira Sasaki  Charles R. Bacon 《Geochimica et cosmochimica acta》2009,73(10):2978-3012

Evaluation of the extent of volatile element recycling in convergent margin volcanism requires delineating likely source(s) of magmatic volatiles through stable isotopic characterization of sulfur, hydrogen and oxygen in erupted tephra with appropriate assessment of modification by degassing. The climactic eruption of Mt. Mazama ejected approximately 50 km³ of rhyodacitic magma into the atmosphere and resulted in formation of a 10-km diameter caldera now occupied by Crater Lake, Oregon (lat. 43°N, long. 122°W). Isotopic compositions of whole-rocks, matrix glasses and minerals from Mt. Mazama climactic, pre-climactic and postcaldera tephra were determined to identify the likely source(s) of H₂O and S. Integration of stable isotopic data with petrologic data from melt inclusions has allowed for estimation of pre-eruptive dissolved volatile concentrations and placed constraints on the extent, conditions and style of degassing.Sulfur isotope analyses of climactic rhyodacitic whole rocks yield δ³⁴S values of 2.8-14.8‰ with corresponding matrix glass values of 2.4-13.2‰. δ³⁴S tends to increase with stratigraphic height through climactic eruptive units, consistent with open-system degassing. Dissolved sulfur concentrations in melt inclusions (MIs) from pre-climactic and climactic rhyodacitic pumices varies from 80 to 330 ppm, with highest concentrations in inclusions with 4.8-5.2 wt% H₂O (by FTIR). Up to 50% of the initial S may have been lost through pre-eruptive degassing at depths of 4-5 km. Ion microprobe analyses of pyrrhotite in climactic rhyodacitic tephra and andesitic scoria indicate a range in δ³⁴S from −0.4‰ to 5.8‰ and from −0.1‰ to 3.5‰, respectively. Initial δ³⁴S values of rhyodacitic and andesitic magmas were likely near the mantle value of 0‰. Hydrogen isotope (δD) and total H₂O analyses of rhyodacitic obsidian (and vitrophyre) from the climactic fall deposit yielded values οf −103 to −53‰ and 0.23-1.74 wt%, respectively. Values of δD and wt% H₂O of obsidian decrease towards the top of the fall deposit. Samples with depleted δD, and mantle δ¹⁸O values, have elevated δ³⁴S values consistent with open-system degassing. These results imply that more mantle-derived sulfur is degassed to the Earth’s atmosphere/hydrosphere through convergent margin volcanism than previously attributed. Magmatic degassing can modify initial isotopic compositions of sulfur by >14‰ (to δ³⁴S values of 14‰ or more here) and hydrogen isotopic compositions by 90‰ (to δD values of −127‰ in this case).  相似文献   

MOA-cam3: a wide-field mosaic CCD camera for a gravitational microlensing survey in New Zealand     

T. Sako  T. Sekiguchi  M. Sasaki  K. Okajima  F. Abe  I. A. Bond  J. B. Hearnshaw  Y. Itow  K. Kamiya  P. M. Kilmartin  K. Masuda  Y. Matsubara  Y. Muraki  N. J. Rattenbury  D. J. Sullivan  T. Sumi  P. Tristram  T. Yanagisawa  P. C. M. Yock 《Experimental Astronomy》2008,22(1-2):51-66

We have developed a wide-field mosaic CCD camera, MOA-cam3, mounted at the prime focus of the Microlensing Observations in Astrophysics (MOA) 1.8-m telescope. The camera consists of ten E2V CCD4482 chips, each having 2k×4k pixels, and covers a 2.2 deg² field of view with a single exposure. The optical system is well optimized to realize uniform image quality over this wide field. The chips are constantly cooled by a cryocooler at ??80° C, at which temperature dark current noise is negligible for a typical 1–3 min exposure. The CCD output charge is converted to a 16-bit digital signal by the GenIII system (Astronomical Research Cameras Inc.) and readout is within 25 s. Readout noise of 2–3 ADU (rms) is also negligible. We prepared a wide-band red filter for an effective microlensing survey and also Bessell V, I filters for standard astronomical studies. Microlensing studies have entered into a new era, which requires more statistics, and more rapid alerts to catch exotic light curves. Our new system is a powerful tool to realize both these requirements.  相似文献